Sunday, April 15, 2012

Direct Dyes

These  colors  are  known  as  substantive  dyes  or  Salt  dyestuffs  or  even  simply  cotton colors. The colors are well known for its use in dyeing cellulose fibres like cotton,  viscose rayon, animal fibres such as wool and silk. Selected substantive dyes can be used  to give solid shades on wool and cotton mixtures. Direct dyes are also called Substantive  dyes because of their excellent substantively for cellulose textile materials like cotton and viscose rayon.

Properties Of Direct Dyes
  • Direct dyes are readily soluble in water.
  • Some of the dyes need a little amount of soda ash (Sodium Carbonate) for complete dissolve them in water.
  • Direct dyes are used for dyeing cotton, viscose rayon, wool and silk fibres.
  • If common salt or Glauber‟s salt (Sodium sulphate) is added to the dye during dyeing, more dye is taken up by the fiber i.e. the dye bath gets exhausted to a greater extent. Hence these salts are exhausting agents for direct while dyeing or cotton. 
  • Direct  dyes  have  poor  washing  fastness  and  poor  light  fastness.  These  fastnessproperties  can  be  improved  by  certain  after-treatments.  If  a  piece  of  cotton  dyedwith a direct dye is boiled with soap and water which contains also a small pieceof un-dyed cotton, the latter generally becomes stained with the dye from former.This is known as bleeding.  
Application of Direct Dyes to Cotton/Viscose 
The dye bath is usually made up with twenty items as much water as the material. Take for example, for 100 kilograms of cotton fabric 2,000 liters of water can be taken. For dyeing only soft water should be used. 

From 0.5 to 5% of the dyestuff according to the shade required to be taken. The  dyestuff  is  pasted  with  cold  water  and  sufficient  boiling  water  is  then  added,  with  constant  stirring  to  bring  it  into  solution.  It  is  then  added  to  the  dye  liquor  through  a  strainer.

Some  direct  dyestuffs  give  better  results  in  a  slightly  alkaline  bath.  In  fact  it  is  advantageous in most cases, since it renders the dyestuff more completely soluble in the  dye bath. From 0.5 to 2% of Sodium carbonate may be used.

The cotton material is wetted out in water and entered into the dye bath at 41ºC to  50  ºC  and  the  liquid  is  raised  to  the boil  over  a  period  of  30  to  40  minutes  and  then  common salt or Glauber‟s salt is added to the dye bath for the complete exhaustion of the dye bath.  These salts are exhausting agents for direct dyes while dyeing on cotton. The dyeing is continued at the boil for ¾ to 1 hour.  At the end of the dyeing the material is rinsed in cold water and dried without soaping.  Direct  dyes  have  poor  washing  fastness  and  poor  light  fastness.  However,  these fastness properties can be improved by certain after treatments.

After Treatments
A dye fixing treatment  may  give in  a fresh bath containing  a cationic dye-fixing agent before drying; this process improves the wet fastness of the dyed goods. Fastness  properties  of  Direct  dyed  goods - Both  washing  and  light  fastness  of most of the direct dyed goods are generally poor; to improve the fastness properties after  treatments may be given improve the fastness

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